Titration is a method that is used to calculate the unknown analyte concentration. In this method, the solution with a known concentration is taken in the burette while the solution from where the concentration has to be analyzed is taken in the conical flask with the use of a pipette. An indicator is also used for most of the titration reaction to understand the endpoint or the point at which the reaction completes. Titrimetric analysis is done by different methods using different types of titrant and analyte. These are mainly acid-base titration, redox titration, precipitation titration, and so on.
Acid-base titrations are those that consist of an acid and base mixed together to carry out a neutralization reaction. Usually, in this titration method, an indicator is used to understand the endpoint. There are mainly four types of acid-base titrations, which are as follows:
Strong acid-Strong base: This titration reaction occurs between a strong acid and a strong base. In this type of titration, a neutral solution is formed as a result of the reaction. Salt and water are produced as products.
Strong acid-Weak base: In this process of titration, a strong acid and a weak base are involved, which leads to the formation of an acidic solution. This is a result of the formation of a conjugate acid that is converted to hydronium ions in water.
Weak acid- Strong base: In this process, a weak acid and a strong base are involved, which combines to form a basic solution. This is a result of the formation of a conjugate base that is converted to hydroxide ions in water.
Weak acid- Weak base: This titration reaction occurs between a weak acid and a weak base. In this type of titration, the strength of the solution is dependent on the concentration of the acid and the base used.
Redox titration is a type of titration where a redox reaction takes place between the titrant and the analyte. Both oxidation, as well as reduction, takes place simultaneously during the titration. This is usually monitored by a potentiometer. The electrons that are transferred from one species to another is tracked. There are mainly four types of redox titrations. These are categorized based on the titrant used. One of the redox reactions is iodometric titration, where the titrant used is iodine. Here, either the appearance or the disappearance of iodine is observed. Bromatometry is another example of redox titration where the titrant is bromine, which is also an indicator. Permaganometry is a redox reaction where potassium permanganate is used as the titrant to calculate the concentration of the analyte. This titration mainly involves two steps. Another important redox reaction is dichrometry, where potassium dichromate is used as a titrant to calculate the concentration of the analyte. These are some important examples of redox titration.
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